Project Abstract

Abstract
Biodiesel is a renewable alternative fuel that can be produced from various feedstocks including vegetable oils. This research project focuses on the optimization of biodiesel production from two non-edible oils, namely yellow oleander oil and castor oil. Yellow oleander oil and castor oil are attractive feedstocks for biodiesel production due to their high oil content and availability. The main objective of this study is to optimize the transesterification process for both oils to maximize biodiesel yield. The optimization process involves the selection of catalyst, molar ratio of oil to alcohol, reaction temperature, and reaction time. Different catalysts such as sodium hydroxide, potassium hydroxide, and calcium oxide will be evaluated to determine the most effective catalyst for the transesterification of yellow oleander oil and castor oil. The molar ratio of oil to alcohol plays a crucial role in the transesterification process as it affects the conversion of triglycerides to biodiesel. The effect of varying the molar ratio on biodiesel yield will be studied to determine the optimum ratio for each oil. Furthermore, the influence of reaction temperature and reaction time on biodiesel production will be investigated. The temperature of the reaction affects the rate of the transesterification reaction, while the reaction time determines the completion of the reaction. By optimizing these parameters, the biodiesel yield from yellow oleander oil and castor oil can be enhanced. In addition to the optimization of biodiesel production, this research project will also involve the analysis of the fuel properties of biodiesel derived from yellow oleander oil and castor oil. The key fuel properties to be evaluated include cetane number, kinematic viscosity, flash point, and higher heating value. These properties are important indicators of the quality of biodiesel and its compatibility with diesel engines. Overall, this research project aims to contribute to the sustainable production of biodiesel by utilizing non-edible oils such as yellow oleander oil and castor oil. The optimization of biodiesel production processes and the evaluation of fuel properties are essential steps towards the commercialization of biodiesel derived from these feedstocks.

Project Overview

1.0 INTRODUCTION

The world energy sector depends on the petroleum, coal and natural gas reservoirs to fulfill its energy requirements (Meher et al., 2006). Nigeria is traditionally an energy-deficient country which exports above 70% of its crude oil production. The country is dependent upon import of petroleum products to sustain its growth. Diesel fuel plays an essential function in the industrial economy of Nigeria. The fuel is used in heavy trucks, city transport buses, electric generators, farm equipment etc. (Anjana, 2000). However, diesel engine also emits various forms of pollutants into the environment which can endanger human health and damage the ecological environment (Antolin et a.l, 2002). It is therefore essential that the world extend its interest towards new sources of energy. A relatively new alternative that is currently booming worldwide is fuel obtained from renewable resources or biofuel. Biofuels are well suited for decentralized development i.e can be utilised to meet the needs for social and economic progress, especially in rural communities where fossil fuels may be difficult or expensive to obtain (Nwafor and Nwafor, 2000; Ezeanyananso et al., 2010).

Amongst the various alternative fuels which could match the combustion features of diesel oil and can be easily adapted for use in existing engine technologies with or without any major modifications is biodiesel. Biodiesel fuel produced from vegetable oils (both edible and non edible) or animal fats is one of the promising possible sources that can be substituted for conventional diesel fuel and produces favourable effects on the environment. Biodiesel is recommended for use as a substitute for petroleum diesel

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mainly because it is a renewable, domestic resource with an environmentally friendly emission profile and is readily available and biodegradable (Zhang et al., 2003).

The research and use of biodiesel fuel as an alternative started in the 1980?s and the reason was the diesel crisis caused by the reduction of petroleum production by the Organization of Petroleum Exporting Countries (OPEC) and the resultant price hike. The biodiesel produced from locally available resources offer a great promise for future application in Nigeria as it can help in attaining much needed energy security and being environment friendly, will help to conform to stricter emission norms (Ezeanyananso, 2010).

Castor plant (Ricininus communis)

Ricinus communis (Plate I) is a species that belongs to the Euphorbiaceae family and it is commonly known as castor oil plant, and Palma christi. Castor oil is possibly the plant oil industry?s most underappreciated asset. It is one of the most versatile of plant oils, being used in over ten diverse industries.

Owing to its unique chemical composition and structure, castor oil can be used as the starting material for producing a wide range of end-products such as biodiesel, lubricants and greases, coatings, personal care and detergent, surfactants, oleo chemicals e.t.c. Compared to many other crops, castor crop requires relatively fewer inputs such as water, fertilizers and pesticides. The crop can also be grown on marginal land, thus providing an excellent opportunity for many regions of the world to utilize their land resources more productively (Dokwadanyi, 2011). The plant prefers well-drained moisture relative clay or sandy loan in full sun requires a rich soil and day time temperature above 20oC for