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Production and performance evaluation of biodiesel from hibiscus sabdariffa and hibiscus surattensis

 

Table Of Contents


<p> </p><p>Cover Page———————————————————————————————i<br>Declaration——————————————————————————————–ii<br>Certification——————————————————————————————iii<br>Dedication——————————————————————————————–iv<br>Acknowledgement———————————————————————————–v<br>Abstract———————————————————————————————–vi<br>Table of Contents———————————————————————————–vii<br>List of Figures—————————————————————————————xii<br>List of Tables—————————————————————————————xiii<br>List of Plates—————————————————————————————–xv<br>List of Appendices———————————————————————————xvi<br>Abbreviation—————————————————————————————xvii<br>

Chapter ONE

<br>INTRODUCTION<br>1.0 Background—————————————————————————————1<br>1.1 Statement of Research Problem—————————————————————-2<br>1.2 Present Research———————————————————————————3<br>1.3 Significance of Research————————————————————————3<br>1.4 Objective——————————————————————————————4<br>1.5 Justification—————————————————————————————5<br>1.6 Methodology————————————————————————————-6<br>– 9 –<br>1.7 Scope———————————————————————————————-6<br>

Chapter TWO

<br>LITERATURE REVIEW<br>2.0 Historical Background of Biodiesel———————————————————–7<br>2.1 Review Past Work in the Area—————————————————————12<br>2.2 Ways of Running Diesel Engine with Biofuel ———————————————14<br>2.2.1 Mixing it ————————————————————————————–15<br>2.2.2 Straight Vegetable Oil ———————————————————————-16<br>2.2.3 Biodiesel or SVO? ————————————————————————–17<br>2.3 Definition and Theory of Combustion Engine ——————————————–18<br>2.3.1 Engines —————————————————————————————18<br>2.3.1.1 The Internal Combustion Engine ——————————————————-18<br>2.3.1.2 External Combustion Engine ————————————————————18<br>2.3.2 Compression Ignition Engine ————————————————————–18<br>2.4 Performance Criteria for Internal Combustion Engine ———————————–20<br>2.4.1 Indicated Power (ip) ————————————————————————21<br>2.4.2 Indicated Mean Effective Pressure (Pi) —————————————————22<br>2.4.3 Brake Power (bp) —————————————————————————-22<br>2.4.4 Brake Mean Effective Pressure (bmep) ————————————————–23<br>3.4.5 Friction Power (fp) ————————————————————————–23<br>2.4.6 Mechanical Efficiency (ô€ŸŸô€¯ ) —————————————————————23<br>2.4.7 Brake Thermal Efficiency (ô€ŸŸô€®»ô€¯) and Indicated Thermal Efficiency (ô€ŸŸô€¯‚ô€¯) ———-24<br>2.4.8 Specific Fuel Consumption (SFC) and Volumetric Efficiency ———————–24<br>– 10 –<br>2.5 Transesterification —————————————————————————–25<br>2.5.1 General Aspects of Transesterification ————————————————–25<br>2.5.2 Transesterification of Vegetable Oils —————————————————–26<br>2.5.2.1 Acid – Catalyzed Processes ————————————————————–27<br>2.5.2.2 Base –Catalyzed Processes ————————————————————–29<br>2.6 Brief Description of the Seed Plants ——————————————————–31<br>2.6.1 Hibiscus Sabdariffa L. ———————————————————————-31<br>2.6.2 Hibiscus Surattensis ————————————————————————33<br>2.7 Description of Oil Extractor ——————————————————————34<br>2.8 Test Engine ————————————————————————————-38<br>

Chapter THREE

<br>MATERIALS AND METHODS<br>3.0 Introduction ————————————————————————————-40<br>3.1 Equipment Used ——————————————————————————-40<br>3.1.1 Determination of Physicochemical Properties ——————————————40<br>3.1.1.1 Viscosity ———————————————————————————–40<br>3.1.1.2 Relative Density —————————————————————————40<br>3.1.1.3 Calorific Value —————————————————————————-40<br>3.1.1.4 Flash Point ———————————————————————————40<br>3.1.1.5 Acid Value ———————————————————————————40<br>3.1.1.6 Saponification Value ———————————————————————41<br>3.1.1.7 Ash Content ——————————————————————————-41<br>3.1.1.8 Carbon Content —————————————————————————-41<br>– 11 –<br>3.1.1.9 Iodine Value/ Number ——————————————————————–41<br>3.1.1.10 Hydrogen Value ————————————————————————-41<br>3.1.2 Oil Extractor ———————————————————————————41<br>3.1.3 Transesterification —————————————————————————42<br>3.2 Seed Collection———————————————————————————42<br>3.3 Method of Extraction of Oil ——————————————————————42<br>3.3.1 Oil Yield of Seeds —————————————————————————42<br>3.4 Physico-Chemical Characterization ———————————————————43<br>3.4.1 Viscosity ————————————————————————————–43<br>3.4.2 Flash Point ———————————————————————————–43<br>3.4.3 Calorific Value ——————————————————————————-44<br>3.4.4 Relative Density —————————————————————————–44<br>3.4.5 Acid Value ———————————————————————————–44<br>3.4.6 Ash Content ———————————————————————————-44<br>3.4.7 Carbon Content ——————————————————————————45<br>3.4.8 Saponification Value ————————————————————————45<br>3.4.9 Iodine Value ———————————————————————————45<br>3.4.10 Hydrogen Content ————————————————————————-45<br>3.5 Methyl Ester Preparation (Transesterification) ——————————————–59<br>3.6 Diesel Fuels and Blend ———————————————————————–59<br>3.7 Experimentation——————————————————————————–60<br>3.7.1 Procedure for Engine Performance Test————————————————–60<br>3.8 Experimental Calculations——————————————————————–61<br>– 12 –<br>

Chapter FOUR

<br>RESULTS AND DISCUSSION<br>4.0 Introduction————————————————————————————-66<br>4.1 Discussion OF Results————————————————————————-81<br>4.1.1 Viscosity—————————————————————————————81<br>4.1.2 Torque—————————————————————————————–81<br>4.1.3 Brake Horse Power————————————————————————–82<br>4.1.4 Fuel Consumption—————————————————————————-82<br>4.1.5 Specific Fuel Consumption—————————————————————–83<br>4.2 Cost Implication——————————————————————————–83<br>

Chapter FIVE

<br>SUMMARY, CONCLUSION AND RECOMMENDATION<br>5.0 Summary—————————————————————————————-84<br>5.1 Conclusion————————————————————————————–85<br>5.2 Recommendation——————————————————————————-86<br>REFERENCES————————————————————————————87<br>– 13 –</p><p>&nbsp;</p><p>&nbsp;</p> <br><p></p>

Project Abstract

<p> </p><p>This work investigated the viability of using locally available vegetable seed oils<br>to produce biodiesel. Two indigenous seeds- Hibiscus Surattensis (Hausa-rahma)<br>and Hibiscus Sabdariffa (Hausa-yakwua) were used to carry out the research.<br>Biodiesel from oils derived from these seeds were produced by alkali catalyzed<br>transesterification process. The physicochemical properties of the oils (such as<br>viscosity, flash point, calorific value, relative density, acid value, ash content,<br>carbon content, saponification value, iodine value and hydrogen content) and<br>various blending ratios of biodiesel with diesel obtained from oils of these seeds<br>were investigated and compared with standard diesel fuel. The methyl esters of<br>the samples were comparatively analysed based on their performance<br>characteristics in blends of 3070, 4060 and 5050 using a Leyland Compression<br>Ignition Engine coupled to a hydro-dynamometer. Parameters like speed of<br>engine and fuel consumption were measured at different loads for pure diesel and<br>various combinations of biodiesel blends. Torque, brake horse power and specific<br>fuel consumption were calculated. The test results indicate that the biodiesel<br>blends of 4060 for H. Sabdariffa has Brake horse power- 12.44kW, Speed-<br>2000rpm, and SFC 0.118 l /kW hr and; 3070 for H. Surattensis has Brake horse<br>power- 13.78kW, Speed-2000rpm, and SFC-0.332 l/kW hr while Diesel has<br>Brake horse power- 10kW, Speed-2000rpm, and SFC-0.193 l/kW hr. Both H.<br>Sabdariffa at 4060 blend and H. Surattensis at 3070 blend have brake horse<br>power and SFC higher than diesel at the speed of 2000rpm hence H. Sabdariffa<br>– 7 –<br>blend of 4060 and H. Surattensis blend of 3070 blend can be recommended for<br>use in diesel engines without making any engine modifications.</p><p><strong>&nbsp;</strong></p> <br><p></p>

Project Overview

<p> INTRODUCTION<br>1.0 BACKGROUND<br>Energy is central to sustainable development and poverty reduction efforts. It affects all<br>aspects of development – social, economic, and environmental – including livelihoods,<br>access to water, agricultural productivity, health, population levels, education, and<br>gender-related issues. The United Nation Millennium Summit identified the most<br>pressing global development needs. These were called Millennium Development Goals<br>(MDGs) which were unanimously adopted by the international community in 2000.These<br>MDGs are a list of human development objectives to be achieved by 2015 (UNDP,<br>2000). These goals include: poverty alleviation, universal basic education for all,<br>promotion of gender equality and empowering of women, improved health conditions<br>and environmental sustainability. None of the MDGs can be met without major<br>improvement in the quality and quantity of energy services in developing countries.<br>UNDP’s efforts in energy for sustainable development support the achievement of the<br>MDGs, especially MDG1, reducing by half the proportion of people living in poverty by<br>2015 (UNDP, 2000).<br>The present study is a research set out to investigate the viability of using some locally<br>sourced vegetable seeds to produce biodiesel or methyl ester from the oils extracted from<br>these local seeds. Different indigenous seeds namely: Hibiscus Surattensis and Hibiscus<br>Sabdiraffa seeds were used to carry out the research work. The physicochemical<br>properties of the biodiesel obtained from the oil of these seeds were investigated and<br>– 21 –<br>compared with standard diesel fuels. The fuels were used to run a diesel engine and the<br>performance of the Diesel Engine was observed.<br>1.1 STATEMENT OF RESEARCH PROBLEM<br>1. Nigeria today is possibly facing the worst energy crisis ever to befall this nation.<br>The country, by the government’s admission, imports about 70% of refined fuel needed<br>for domestic consumption. Despite the award of licenses to several private firms to build<br>refineries, absolutely no investor has committed a farthing to construction (This Day<br>Newspaper, 2007).<br>2. Numerous studies indicated that oil sources in the world will come to an end. As a<br>result, new alternative energy sources will be required to substitute for Fossil diesel<br>(Yücesu et al., 2006).<br>3. Due to rising dangers from the ongoing build up of human-related greenhouse gases<br>produced mainly by the burning of fossil fuels and forests, it has become necessary to<br>develop alternative fuels that will be environmental friendly.<br>A possible solution to a potential future energy shortage would be to use some of the<br>world’s remaining fossil fuel reserves as an investment in renewable energy<br>infrastructure such as wind power, solar power, tidal power, geothermal power,<br>hydropower, methanol, ethanol and biodiesel, or in an oil lamp; olive oil, canola oil,<br>safflower oil, or sunflower oil which do not suffer from finite energy reserve but do not<br>– 22 –<br>have finite energy flow. The construction of sufficiently large renewable energy<br>infrastructure might avoid the economic consequences of an extended period of decline in<br>fossil fuel energy supply per capita.<br>1.2 PRESENT RESEARCH<br>The present study is a research set out to investigate the viability of using some locally<br>sourced vegetable seeds to produce biodiesel or methyl ester from the oils extracted from<br>these local seeds. Different indigenous seeds namely: Hibiscus Surattensis and Hibiscus<br>Sabdiraffa seeds were used to carry out the research work. The physicochemical<br>properties of the biodiesel obtained from the oil of these seeds were investigated and<br>compared with standard diesel fuels. The fuels were used to run a diesel engine and the<br>performance of the Diesel Engine was observed.<br>1.3 SIGNIFICANCE OF RESEARCH<br>The use of renewable fuels on a more significant scale than at present would reduce<br>dependence on fossil fuels, thereby reducing the associated environmental impacts.<br>Biodiesel, a renewable energy source, could supplement the energy needs of the<br>economy, with relatively minimal impact on to the environment.<br>Recent survey has indicated that with the present rate of energy consumption, there is<br>combined decline in quantity of crude petroleum which serves as source for diesel oil<br>– 23 –<br>production. Moreover, the rate of discovery of petroleum deposits is not proportional to<br>the rate of consumption (George, 2005).<br>Through its environmental relations, the immediate and past impact effect of oil spillage<br>and pollution has done much to destroy the live of the communities, vegetation and<br>aquatic lives (George, 2005).<br>Also, Biodiesel improves lubricity and reduces premature wearing of diesel engine fuel<br>pumps (Schumacher and Howell, 1994).<br>The above mentioned problems and other facts, necessitate further research or rather<br>awakened new interest for vegetable oil improvement as alternative source. This potential<br>energy source is renewable. It could reduce risk of unavailability of fossil diesel and<br>could to a large extend reduce pollution effects resulting from their waste. Furthermore,<br>there is no doubt that this will boost agriculture as more seeds will be required. A greater<br>percentage of the populace live in the rural areas and as they cultivate these crops as raw<br>materials for Biodiesel production, it will boost their economic power and poverty will be<br>reduced thereby helping to achieve one of the MDGs.<br>1.4 AIM AND OBJECTIVES<br>The aim of this work is to establish the possibility of using Hibiscus Surattensis and<br>Hibiscus Sabdariffa methyl esters as alternative fuels in diesel engine. The specific<br>objectives are:<br>i. to investigate the physicochemical properties of vegetable oils from Hibiscus<br>– 24 –<br>Surattensis and Hibiscus Sabdariffa seeds.<br>ii. to convert the oils to biodiesel by the process of transesterification, and then compare<br>their physicochemical properties with those of petroleum- based diesel.<br>iii. to test the performance of the biodiesel from these oils at various blend ratios with<br>diesel using the Leyland Compression Ignition Engine.<br>iv. to establish the optimum blend of the biodiesel.<br>1.5 JUSTIFICATION<br>In the year 2000, there were about eight million vehicles around the world that ran on<br>alternative fuels, indicating sustainability (Fight Global Warming, 2007).<br>The major environmental concern, according to an Intergovernmental Panel of Climate<br>Change (IPCC) report, is that “most of the observed increase in globally averaged<br>temperatures since the mid-20th century in due to the observed increase in anthropogenic<br>greenhouse gas concentration” which is due to burning of fossil fuels (National Energy<br>Information Center 2004).<br>Another concern is the peak oil theory, which predicts a rising cost of oil derived fuels<br>caused by severe shortage of oil during an era of growing energy consumption. The<br>demand for oil will exceed supply and this gap will continue to grow, which could cause<br>a growing energy crisis starting between 2010 and 2020 (Hirsch, 2006).<br>Economic consideration- According to survey carried out in the US, biodieselers (people<br>who brew biodiesel domestically) using waste oil feedstock make biodiesel for 50 cents<br>– 25 –<br>to US $1 per US gallon (<a target="_blank" rel="nofollow" href="http://journeytoforever.org)">http://journeytoforever.org)</a>. It still went further to report that<br>most people in the US use about 600 gallon of fuel a year (about 10 gallon a week),<br>costing about US$1,800 a year (mid-2007). Petro-diesel costs about three times more in<br>the other industrialized countries (in UK in mid-2007 it cost the equivalent of US$7.37<br>for a US gallon of Petro-diesel) but those countries generally use less fuel than the US.<br>This means that biodieselers will be paying $300-360 for their fuel<br>(<a target="_blank" rel="nofollow" href="http://journeytoforever.org)">http://journeytoforever.org)</a>.<br>1.6 METHODOLOGY<br>This has to do with the methods used and the procedures adopted to extract each of the<br>oils: the seeds collection, extraction of oils, their physicochemical properties,<br>Transesterification, and experimentation based on the application of these samples in the<br>diesel engine to test their performance characteristics.<br>1.7 SCOPE<br>The present work compares the performance of various biodiesels with fossil diesel using<br>a Leyland four stroke Compression Ignition Engine (CIE) coupled to a hydro<br>dynamometer. The goal of this work is also to determine the physicochemical properties<br>of the vegetable oils and the biodiesel obtained from the oils which were then compared<br>with that of standard petrol diesel. The performance will determine the suitability of these<br>biodiesel fuels for use in a diesel engine. <br></p>

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