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Recycling of polyethylene waste materials to useful products via pyrolysis.

 

Table Of Contents


Thesis Abstract

Abstract
The recycling of polyethylene waste materials through pyrolysis has gained significant attention in recent years as a sustainable approach to manage plastic waste. Pyrolysis is a thermochemical decomposition process that breaks down the long-chain polymer molecules of polyethylene into smaller hydrocarbon molecules in the absence of oxygen. This process offers a promising method to convert polyethylene waste into valuable products such as liquid fuels, gases, and solid residues. Various pyrolysis techniques have been developed to optimize the conversion of polyethylene waste materials into useful products. The choice of pyrolysis technique depends on factors such as temperature, heating rate, residence time, and the type of catalyst used. Slow pyrolysis involves heating the polyethylene waste materials at a low temperature (less than 300°C) for an extended period, resulting in the production of biochar and pyrolysis oil. Fast pyrolysis, on the other hand, operates at higher temperatures (between 400-600°C) with short residence times, leading to the production of bio-oil with higher yields. The liquid products obtained from polyethylene pyrolysis have the potential to be used as fuels or as feedstock for the production of chemicals. The gaseous products, such as methane, ethylene, and propylene, can be utilized as fuel or for further chemical processing. The solid residues, known as char or biochar, can be used as a soil amendment or activated carbon. Additionally, the by-products of polyethylene pyrolysis can be further refined to increase their value and applicability. The environmental benefits of recycling polyethylene waste through pyrolysis include reducing the amount of plastic waste in landfills, decreasing greenhouse gas emissions, and conserving energy resources. Furthermore, the conversion of polyethylene waste into useful products via pyrolysis contributes to the circular economy by closing the loop on plastic materials and promoting a more sustainable approach to waste management. In conclusion, the recycling of polyethylene waste materials to useful products through pyrolysis is a promising technology with the potential to address the growing concerns of plastic pollution and resource depletion. Continued research and development in this field are essential to optimize the pyrolysis process, improve product yields, and explore new applications for the recovered products.

Thesis Overview

1.0 INTRODUCTION

1.1 BACKGROUND OF STUDY

Recycling is a dynamic process that restores the life cycle of a material. Also recycling refers to as a process of collecting and processing materials that would otherwise be thrown away as trash and turning them into a new product. Recycling as well reduce the consumption of fresh raw materials, energy usage, water and air pollution and lower green house gas emission as compared to a plastic production. (Roach John 2003).

Polyethylene plastic bags are petroleum-based so the manufacturing process releases harmful pollutants into the atmosphere. Some speculate that these emissions and other smog-related types of pollution accumulate over time in the atmosphere.                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                    Uioolk1

Countries and large corporations are beginning to realize the threat that these plastic bags pose to our planet. Many are proposing or have already enacted laws and taxes to decrease the use of polyethylene plastic bags. Many grocery stores are even rewarding customers for bringing reusable grocery bags as an alternative to these polyethylene plastic bags. Customers choosing not to use alternatives to plastic bags either find the alternatives are inconvenient or are simply unaware of the problem at hand.

Polyethylene recycling bags are currently being used all over the world but there is currently no environmentally friendly way to dispose of them.

The rate of consumption of plastic materials in the world is highly expanding, more waste plastics are generated. In past years, their generation amount in China becomes about six million per year, according to data from the National Institute of Environmental Research (Roach John 2005).

Typically, raw materials are manufactured into products for consumption. Leftovers are then thrown away. This linear process, from extraction of raw materials, to production, then consumption and disposal, has created a waste crisis.

To reduce this one-way flow of re-sources to overburdened waste disposal facilities, materials no longer needed or wanted can be remanufactured. (Roach John 2003).

1.2 AIM

The aim is to recycle polyethylene waste materials to useful products via pyrolysis.

1.3 OBJECTIVES

The objectives of this work are includes:-

(a). To collect the polyethylene waste materials (discarded water sachets plastic bottle )

(b). To carry out thermal pyrolysis of the materials at temperature of 300oC – 350oC

 (c). To monitor the quantity of fuel gas and hydrocarbon liquids evolved

1.4 SIGNIFICANCE OF THE STUDY

The significance studies of recycling polyethylene waste materials via pyrolysis are:

It serve as an economics important to the society or nations

The recycling of polyethylene waste materials to useful appear intervene with our consuming society where it will be hard to imaging in modern society today without plastic which have found amyriad of used in fields as diverse as household appliance, packaging, construction, medicine and electronic.

The recycling of polyethylene waste help in an industrial production of plastic and polymer products such as sachet water, plastic bottle, rubber paint, e.t.c. As sources of raw materials to produces other useful product from those polyethylene waste materials.

It helps in prevent waste pollutant from an environment.

1.5 SCOPES OF THE STUDY

The research is restricted to the recycling of polyethylene products, arising specifically from Low Density Polyethylene (LDPE). No attempt is made to suggest new production process. the study does not include of alternative materials.  



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